3M New Zealand Limited, 94 Apollo Drive, Rosedale, Auckland 0632 New Zealand Phone (09)477 4040 ======================================================================== Safety Data Sheet ======================================================================== Document id : 18-8617-5 Issue date : 13/05/2011 Version : 1.02 Supersedes date : 13/05/2011 This SDS has been prepared by 3M New Zealand Limited Toxicology Dept. 1 PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M INTERAM ULTRA GS WITH SCRIM 3M Product ID 98-0400-5398-9, 98-0400-5566-1, 98-0400-5567-9, 42-0013-3695-9, 42-0016-4723-1, 42-0016-4749-6, 44-0029-8115-5, 44-0029-8124-7, 44-0029-8125-4, 44-0029-8140-3 Intended Use of Product: Fire Protection Supplier Details: 3M New Zealand Limited, 94 Apollo Drive, Rosedale, Auckland 0632 New Zealand. Phone: (09) 477 4040 24 hr Emergency phone number: 0800 764766 (0800 POISON) 2 HAZARDS IDENTIFICATION ------------------------------------------------------------------------ NOTE: Classified as hazardous according to the New Zealand Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001. Not classified as a Dangerous Good according to NZS 5433:2007 Transport of Dangerous Goods on Land, UN, IMDG and IATA. HSNO Hazard Classifications: 6.7B, 6.9A, 9.1C GHS Classification GHS Classification - Physical NONE ALLOCATED GHS Classification - Environmental Acute Aquatic Toxicity: Category 3. Chronic Aquatic Toxicity: Category 3. GHS Classification - Health Carcinogenicity: Category 2. Specific Target Organ Toxicity (repeated exposure): Category 1. Signal Word DANGER! Symbols Health Hazard | Hazard Statements - Physical NONE ALLOCATED Hazard Statements - Environmental H412 Harmful to aquatic life with long lasting effects. Hazard Statements - Health H351 Suspected of causing cancer. Hazard Statements - Target Organ, Single Exposure, Category 1 NONE ALLOCATED Hazard Statements - Target Organ, Single Exposure, Category 2 NONE ALLOCATED Hazard Statements - Target Organ, Single Exposure, Category 3 NONE ALLOCATED Hazard Statements - Target Organ, Prolonged or Repeated Exposure, Category 1 H372 Causes damage to organs through prolonged or repeated exposure: respiratory system | Hazard Statements - Target Organ, Prolonged or Repeated Exposure, Category 2 NONE ALLOCATED Precautionary Statements - General NONE ALLOCATED Precautionary Statements - Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P281 Use personal protective equipment as required. P270 Do not eat, drink or smoke when using this product. P264 Wash thoroughly after handling. P273 Avoid release to the environment. Precautionary Statements - Response P308 + P313 IF exposed or concerned: Get medical advice/attention. Precautionary Statements - Storage NONE ALLOCATED Precautionary Statements - Disposal P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Unknown % Acute Lethality 6.99% of the mixture consists of ingredients of unknown acute oral toxicity. Unknown % Environmental 6.99% of the mixture consists of ingredients of unknown hazards to the aquatic environment. 3 COMPOSITION ------------------------------------------------------------------------ Ingredient name CAS number % ------------------------------------- ------------------ ------------- Graphite 7782-42-5 55 - 65 Aluminium trihydroxide 21645-51-2 15 - 25 Proprietary vinyl acetate polymer Trade Secret 5 - 10 Propene Polymer Backing 9010-79-1 1 - 5 Cellulose 9004-34-6 1 - 5 Ethylhexyldiphenyl Phosphate 1241-94-7 1 - 5 Microfibers 65997-17-3 1 - 5 WATER 7732-18-5 1 - 5 4 FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. Instructions for Ingestion No need for first aid is anticipated. Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. Work Place Facilities Required A product risk assessment is recommended to determine if eye wash facilities may be required when using this product in the workplace. 5 FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Exposure Hazards during Fire No unusual fire or explosion hazards are anticipated. Material will not burn. Combustion Products from Fire Combustion Products from Fire are listed in Section 10, STABILITY AND REACTIVITY. Fire Fighting Procedures Wear full protective equipment and a self-contained breathing apparatus. 6 ACCIDENTAL RELEASE MEASURES ------------------------------------------------------------------------ Methods for Disposal Not applicable. 7 HANDLING AND STORAGE ------------------------------------------------------------------------ Refer SDS Section 15 - HSNO Controls For More Information Use Instructions Avoid breathing of dust created by cutting, sanding, grinding or machining. This product is considered to be an article which does not release or otherwise result in exposure to a hazardous chemical under normal use conditions. Incompatible Materials Store away from acids. Approved Handler Test Certificate Not required 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ------------------------------------------------------------------------ Microfibers (65997-17-3) 3M - TWA 10 mg/m3 3M: TWA; as dust; Comments: nuisance particulate. Recommended Ventilation Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with dust or airborne particles. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields. Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance specifications of AS/NZS 1337. Hand Protection Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Skin Protection Not applicable. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance specifications. For information on respirators, call 3M on (09) 477 4040. Ingestion Not applicable. 9 PHYSICAL/CHEMICAL PROPERTIES ------------------------------------------------------------------------ - Appearance and Odour: Solid. Gray to black solid composite with little or no odour. - Odour Threshold: Not determined. - pH: Not applicable - Boiling point/boiling range: Not applicable - Melting point/melting range: Not applicable - Flash point: Not applicable - Autoflammability: Not applicable - Flammable Limits - LEL: Not applicable - Flammable Limits - UEL: Not applicable - Vapour pressure: Not applicable - Water Solubility: Nil - Specific gravity: Not applicable - Vapour density: Not applicable - Relative Density: Not determined. - Percent Volatile: Not determined 10 STABILITY AND REACTIVITY ------------------------------------------------------------------------ Stability and Reactivity Hazardous polymerisation will not occur. Stable. Conditions to Avoid None known. Materials to Avoid Strong acids. Hazardous Decomposition Carbon monoxide - During Combustion. Carbon dioxide - During Combustion. Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. 11 TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Delayed Dermal Irritation: Signs/symptoms may include localised redness, swelling, itching, and pain. These effects may not appear immediately following exposure. Effects from Inhalation Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. - Dust from cutting, grinding, sanding or machining may cause target organ effects. During grinding, scraping, sanding: Fibrosis: Signs/symptoms may include breathlessness, chronic dry cough, phlegm production, wheezing, and changes in lung function tests. Lung Effects: Signs/symptoms may include difficulty breathing, cough, wheezing, weakness, increased heart rate, bluish coloured skin (cyanosis), sputum production and changes in lung function tests. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhoea and vomiting. Numerical Measures of Toxicity Not determined. 12 ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data Not determined. Mobility in Soil and Water Not determined. Persistence/Biodegradability Not determined. Bioaccumulation Potential Not determined. Ecotoxicity Data Not determined. Ecological Fate Data Not determined. 12.7 Special statements for 2001/58/EC: Not determined. 13 DISPOSAL CONSIDERATIONS ------------------------------------------------------------------------ Product as Sold Dispose of waste product in a sanitary landfill. As a disposal alternative, incinerate in an industrial or commercial facility. Product in Use Not determined. Product after Use Not determined. Product Packaging Packaging (that may or may not contain any residual substance) maybe lawfully disposed of by householders or other consumers through public or commercial waste collection services. Potential for Recycling Not determined. 14 TRANSPORT INFORMATION ------------------------------------------------------------------------ New Zealand Land Transport (Road/Rail) UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED IATA (Air Freight) UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED IMO (Sea Freight) UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED 15 REGULATORY INFORMATION ------------------------------------------------------------------------ ERMA New Zealand HSNO Approval Number: HSR002545 HSNO Hazard Classifications - refer to Section 2. HSNO Controls: Approved Handler Test Certificate Not required Location and Transit Depot Test Certification Not required Hazardous Atmosphere Zone Not required Fire Extinguishers Not required Emergency Response Plan 1000L or 1000Kg (for a HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance) Secondary Containment 1000L or 1000Kg (for a HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance) Tracking Not required Warning Signage 1000L or 1000Kg (for a HSNO 8.3A, 9.1B or 9.1C substance) 16 OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Initial Issue The information in this Safety Data Sheet (SDS) is believed to be correct as of the date of issue. 3M MAKES NO WARRANTY, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY,(UNLESS REQUIRED BY LAW) OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,some of which are uniquely within the user's knowledge and control, it is essential that the user evaluates the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to customers.Due to the remote possibility of electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M SDSs are available at www.3M.com.